I always buy my textbooks at the ASU bookstore. I have always been greeted with big smiles when I walk in and there are plenty of employees that are more than happy to walk around with you to help navigate the maze and find what you are looking for, double check the ISBN numbers, etc. I also appreciate that at the checkout they are really diligent about offering the option to rent certain books (only some can be rented rather than bought), you can save a lot by renting books, just bring them back at the end of the semester.
I have also ordered items online before from the ASU bookstore and had them shipped to family across the country and found the process to be easy and everything arrived quickly and packaged nicely.