This Starbucks is hidden away on the south side of Camelback. I don't see any parking lot close, but there might be one with the AMC theaters. The location likely caters to the working crowd in the nearby offices.
If you are shopping at Biltmore, there is a Starbucks in Macy's but instead walk under Camelback and visit this location. It has a large outdoor seating area. The actual indoor seating space is rather small, but they have arranged the furniture for maximum occupancy.
Baristas are friendly and make a good Starbucks drink.