Collectivo on State offers a charming, but busy place to get coffee. I've tried their black coffee and espresso, both of which are pretty good; though their espresso is quite bitter, very different from Starbucks! Their baked goods, including coffee brownies and croissants are also pretty good. I haven't tried their hot sandwiches, but they did look pretty good.
The building itself is new and modern, with loft seating and an outdoor patio when it's warm enough.