I recommend you try Matador if your at 32st and Union Hills. I used to live very close to this little coffee shop. The owners used to roast their own coffee here but have moved that operation to a better location. Their coffees are really good.
They have a liquor license for a full bar with a minimal essential stock of beer and luxury spirits. I order a breakfast egg sandwich which was delicious. The young gal that slaved for me was super cool.
Paradise Valley Community College is right next door to the South, so this is a good study hall.