I love Lola's on Central. Great location that's not too far away from the Biltmore. Unless it's super packed at Hula's for some reason, you should always be able to find a space to park.
There's plenty of spaces to sit and work with their free Wi-Fi. I particularly liike working at the "bar" that overlooks Central. Their music is kind of hipster-y, which is appreciated in a coffee shop, especially if you've spent too many days at Starbucks like I have. However, the music is a little loud in case you want a quieter place to work out of.
There's also cute seating outside for a perfect weekend date coffee shop.
The blanco is my favorite - sort of a white mocha concoction which I'm sure is over anyone's caloric intake for the morning, but a great drink nonetheless.
They've got a ton of pastries, but unfortunately gluten free goodies every now and then. If Lola's would offer that - it would be totally perfect!