Premier Moisson is the go-to bakery/cafe in the neighbourhood. They are open late and have a good collection of breads (including one with no ingredients that contain gluten). They also have a few gluten-free pastries. The breads are pretty good and the pastries are enjoyable - though not the best in town. Nevertheless, I'll pick them over any nonlocal chain coffee place anytime. This is quite a spacious bakery and there's ample space to sit with some outlets for those of us accompanied by our laptops! They have a good variety of lunch items as well: different soups, salads and sandwiches etc.
There was a cozy beautiful bakery right in front of them that sadly moved recently. So this is my new fav. bakery/cafe close to villa-maria metro station :)